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Kind of bizarre plotbunny...
Thanks to the opening of this week's Agents of S.H.I.E.L.D. (the montage set to this song), I have this bizarre scenario going round my head of a '60s London-set spinoff featuring Simmons as an Emma Peel-type in Mary Quant dresses.
Maybe an AU.
It's a crazy idea, but it could just work.